Mingos D. Michael P. Comprehensive Organometallic Chemistry III - From Fundamentals to Applications in 13v. Vol. 08 - Compounds of Group 10 2007 [pdf 672sc 673c. 11,46mb] This volume reviews the theory, preparation, properties, reactions and applications of group 10 organometallic compounds. Each chapter concentrates on either Nickel, Palladium or Platinum and examines the different complexes formed with various types of ligands. It provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds.- Valuable content available May 2009 as an individual volume- Separate volumes will appeal to a wider chemistry and materials science audience- Priced for individual researcher as well as library purchase

lgrsnf/A:\usenetabtechnical\Comprehensive Organometallic Chemistry 3ed Vol 08 Grp 10(Elsevier 2007).pdf

nexusstc/Comprehensive Organometallic Chemistry 3ed Vol 08 Grp 10/830c1d69687609a2b5a007a84cc971f8.pdf

Comprehensive organometallic chemistry : the synthesis, reactions, and structures of organometallic compounds

Applications III: functional materials, environmental and biological applications

Comprehensive Organometallic Chemistry Iii, 13 Vol. Set (Hb)

Comprehensive organic functional group transformations II

Comprehensive Organometallic Chemistry 3ed Vol 08 Grp 10

Edward W. Abel, Sir Geoffrey Wilkinson, F. Gordon A. Stone

ed.-in-chief D. Michael P. Mingos, Robert H. Crabtree

Geoffrey Wilkinson; F. Gordon A Stone; Edward W Abel

Geoffrey Wilkinson, E. W. Abel, F. G. A. Stone

Alan R Katritzky; Richard J. K Taylor

David M. P Mingos; Robert H Crabtree

Robert H Crabtree; D. M. P Mingos

Robert Crabtree, Mike Mingos

Amsterdam ; Elsevier, C2007.

Woodhead Publishing Ltd

Elsevier Technical

John Murray Press

Pergamon Press

Focal Press

РГБ

Comprehensive Organometallic Chemistry, 8, 3, 2007

1st ed., Amsterdam, Boston, Netherlands, 2007

1st ed, Oxford [Oxfordshire] ; New York, 1982

United Kingdom and Ireland, United Kingdom

First edition, Amsterdam ; Boston, 2007

Amsterdam [etc.], Netherlands, 2007

1st ed, Amsterdam, 2005

1st ed, Amsterdam, 2008

М, Russia, 2007

Dec 15, 2006

usenet tech -- 2012-06

lg907328

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Comprehensive Organometallic Chemistry III.pdf......Page 1
Introduction......Page 2
Complexes with Carbonyl Ligands......Page 3
Complexes with Carbon Dioxide and Related Ligands......Page 6
Complexes with Isocyanide Ligands......Page 7
Nickel(0) complexes stabilized by carbene ligands......Page 8
Nickel(ii) complexes stabilized by carbene ligands......Page 11
Complexes with Carbonyl Ligands......Page 14
Complexes with Isocyanide Ligands......Page 17
Clusters with Carbonyl Ligands......Page 18
Clusters with Isocyanide Ligands......Page 19
Theoretical and Physical Studies of Nickel Carbonyls......Page 20
Carbon-carbon bond formation: hydrocarbation reactions......Page 21
Carbon-carbon bond formation: cyclization reactions......Page 22
Isomerization, polymerization, other C-C and C-N coupling reactions......Page 24
Catalytic carbon-halogen bond activation with nickel carbene complexes......Page 25
References......Page 26
Introduction......Page 28
Ligand-Free and Solvated sigma-Organonickel Complexes......Page 29
Synthesis of Simple Ni(R)XLn and NiR2Ln Compounds......Page 36
Synthesis by transmetallation......Page 41
Synthesis by oxidative addition......Page 45
Synthesis by electrophilic attack to Ni(0) and NiR2 complexes......Page 51
Synthesis from a sigma-organonickel precursor......Page 53
Preparations not involving a sigma-organonickel precursor......Page 61
Synthesis of Cyclometallated Complexes, Ni(C-chelate)X(L)......Page 64
Reactions in which the Ni-C bond is not involved......Page 71
Reactions in which new Ni-C bonds are formed......Page 76
Reactions in which the Ni-C bonds are displaced......Page 80
Nickel alkyl and aryl complexes in olefin polymerization and oligomerization catalysis......Page 85
Metallacycles......Page 90
Synthesis......Page 94
Reactivity......Page 100
eta3-Allyl-, eta5-Cyclopentadienyl-, and eta-Indenylnickel Complexes with sigma-Bonded Carbon Ligands......Page 106
Homometallic Clusters......Page 112
Heterometallic Clusters......Page 116
Nickel Alkyl and Aryl Complexes in Oxidation States i, iii, and iv......Page 118
Nickel Organometallic Complexes with Macrocyclic Ligands......Page 121
Models of the Carbon Monoxide Dehydrogenase - AcetylCoA Synthase (COD/ACS)......Page 125
References......Page 126
Nickel-Carbon pi-Bonded Complexes......Page 134
Theoretical and physical studies......Page 135
Nickel-ethylene complexes......Page 136
Monometallic nickel-alkene complexes......Page 137
Polymetallic (cluster) Ni-alkene complexes......Page 140
General comments......Page 141
Theoretical and physical studies......Page 142
Monometallic nickel-alkyne complexes......Page 143
Multimetallic Ni-alkyne complexes......Page 146
Ni-cycloalkyne complexes......Page 148
General comments......Page 151
Synthetic and reactivity studies......Page 152
General Comments......Page 159
Theoretical and Physical Studies......Page 160
Substituted nickelocenes and related mixed-sandwich complexes......Page 161
Monometallic complexes of Cp and its substituted derivatives......Page 163
Cationic complexes of the type [CpNiLL’hairsp]+......Page 168
Donor-functionalized CpandL complexes......Page 169
Products arising from reactions of nickelocene......Page 170
Multimetallic derivatives from non-nickelocene sources......Page 175
General comments......Page 176
NiInd2 and Its derivatives......Page 178
NiX(Ind)L complexes......Page 179
Structural features......Page 180
Reactivities......Page 181
Complexes of eta5-Carborane Ligands......Page 183
Theoretical and physical studies......Page 187
Synthetic and reactivity studies......Page 188
References......Page 191
Homoleptic Carbonyls......Page 198
Bonding of CO to Palladium Surfaces......Page 200
Insertion of CO in Pd(ii) Alkyl, Aryl, Alkoxide, and Aryloxide Complexes......Page 201
Insertion of CO from Five-coordinate Intermediates......Page 204
Mononuclear Carbonyls......Page 205
Homonuclear Carbonyl Dimers......Page 207
Higher Nuclearity Homopalladium Clusters......Page 208
Heterometallic Dimers and Clusters......Page 211
Non-heteroatom Carbene Complexes......Page 218
Complexes Stabilized by One Heteroatom (Fisher-type Carbenes)......Page 219
Introduction......Page 220
Formation of complexes via free carbene......Page 221
In situ deprotonation of azolium salts in the presence of a suitable metal fragment......Page 222
Carbene-transfer reactions......Page 224
Miscellaneous methods......Page 225
Functionalized carbenes......Page 226
Chiral carbenes......Page 230
Complexes of NHCs with a non-imidazole core......Page 233
Fundamental studies on properties and reactivity of NHC complexes and related species......Page 235
Cross-coupling reactions......Page 239
Functionalized carbenes in catalysis......Page 242
CO/ethylene co-polymerization......Page 243
C-H activation of methane......Page 244
Novel catalytic applications......Page 245
Supported/two-phase catalysis......Page 246
Synthesis of Complexes......Page 247
Isocyanide-insertion reactions......Page 254
N-heterocyclic and acyclic carbene formation......Page 259
Isocyanide Complexes in Catalysis......Page 260
References......Page 261
Palladium-Carbon sigma-Bonded Complexes......Page 270
Hydrocarbylpalladium(0) and Palladium(i) Complexes......Page 271
Synthesis of Alkynylpalladium(ii) Complexes......Page 272
Reactions and Mechanism Involving Alkynylpalladium(ii) Complexes......Page 274
Metallodendrimers and Polymers Involving Alkynylpalladium Complexes......Page 276
Synthesis of Alkenylpalladium(ii) Complexes......Page 278
Reactions Involving Intermediate Alkenylpalladium(ii) Complexes......Page 280
Palladacycles Derived from Amines or Pyridines......Page 281
Imine- and Oxime-based Palladacycles......Page 286
Palladacycles Containing N-N or N=N Bonds......Page 289
Palladacycles Containing Pd-P Bonds......Page 290
Palladacycles Containing Pd-S Bonds......Page 291
C,C-Chelating Ligands......Page 292
Ferrocene-based Palladacycles......Page 293
Palladacycles Derived from Heterocycles......Page 294
Resolution and Determination of Enantiomeric Purity of Compounds Using Palladacycles......Page 296
Insertion Reactions into Palladacycles......Page 297
Four-membered Palladacycles......Page 298
Palladium(iv) Complexes......Page 299
Palladium(iv) Complexes with Bidentate Nitrogen Ligands......Page 300
Palladium(iv) Complexes with Tridentate Nitrogen Ligands......Page 302
Palladium(iv) Complexes with Phosphine Ligands......Page 304
Other Palladium(iv) Complexes......Page 305
Palladium(iv) Complexes as Intermediates in Synthesis and Catalysis......Page 306
References......Page 307
Introduction......Page 316
General Comments......Page 317
Alkene Complexes of Pd(0)......Page 318
Complexes of Pd(ii) with chelating dienes......Page 329
Complexes of Pd(ii) with monoenes involved in chelate coordination......Page 332
Complexes of Pd(ii) with monoenes......Page 333
Cyclobutadiene Complexes of Pd and Derivatives......Page 334
Complexes of Arenes and Extended Conjugated Alkene Systems......Page 335
pi-Complexes of Fullerenes......Page 349
Structure and Bonding......Page 353
Alkyne Complexes of Pd(0)......Page 354
Alkyne Complexes of Pd(ii)......Page 357
eta3-Allyl palladium complexes formed by ligand-substitution and metathesis reactions......Page 359
Reactions of monoenes......Page 362
Reactions of dienes......Page 363
Reactions of three- and four-membered cycloalkenes involving ring opening......Page 364
Reactions involving alkynes, isonitriles, and CO......Page 365
Miscellaneous reactions of alkenyl alcohols, alkoxides, ketones, and other O-substituted unsaturated substrates......Page 366
Oxidative addition to Pd(0) complexes......Page 367
Migratory insertion in palladium carbenes......Page 368
Structure and bonding......Page 369
Fluxional behaviour......Page 372
Reactivity......Page 374
Reactions of CO and other unsaturated substrates with Pd eta3-allyl complexes......Page 375
Nucleophilic attack at carbon......Page 376
Reductive elimination......Page 381
Reactivity on the allyl substituents......Page 382
Trimethylenemethane, Oxadimethylenemethane, and Related Complexes......Page 383
eta3-Propargyl/Allenyl complexes......Page 384
Insertion of alkynes into Pd-R bonds......Page 385
Reactions of dienes......Page 386
Isomerization reactions......Page 388
Cyclopentadienyl and Related Palladium Complexes......Page 390
References......Page 393
Platinum Carbonyl Complexes......Page 405
Mononuclear Pt(ii) Carbonyls......Page 406
Mononuclear Pt(iv) Carbonyls......Page 409
Homoleptic platinum carbonyl anions......Page 410
Mixed ligand triangular platinum carbonyl clusters......Page 411
Assorted other platinum carbonyl clusters......Page 414
Heterodinuclear clusters......Page 415
Triangular clusters and their derivatives......Page 417
Higher nuclearity clusters......Page 421
Mononuclear Pt(0) Isocyanides......Page 424
Pt(i) Isocyanides......Page 425
Mononuclear Pt(ii) Isocyanides......Page 428
Pt(iv) Isocyanides......Page 430
Heteronuclear Pt Isocyanides......Page 431
Carbenes without Heteroatom Stabilization......Page 434
NHC complexes from free carbenes or imidazoles......Page 436
Heteroatom-stabilized carbene complexes from nucleophilic attack on isocyanides, alkynes, and carbonyls......Page 437
Heteroatom-stabilized carbene complexes via other routes......Page 439
Properties and Reactivity of Platinum Carbene Complexes......Page 440
References......Page 441
Introduction......Page 445
Pt(i) Complexes......Page 446
Neutral alkylplatinum(ii) complexes - preparation and structure......Page 447
Neutral alkylplatinum(ii) complexes - reactions......Page 456
Cationic alkylplatinum(ii) complexes......Page 459
Alkenylplatinum(ii) Complexes......Page 471
Preparation and structure......Page 475
Halogenoaryl complexes......Page 483
Complexes with arylene, bisaryl, and macrocycles......Page 491
Arylplatinum(ii) complexes - reactions......Page 495
Platinacycles with two Pt-C sigma-bonds......Page 498
Platinacycles with one Pt-C sigma-bond and Pt-C pi-bonds......Page 502
Platinacycles with one Pt-C sigma-bond and Pt-O (or S) bonds......Page 505
Platinacycles with one Pt-C sigma-bond and Pt-N (or P) bonds......Page 508
Platinum(ii) complexes with tridentate ligands......Page 522
Alkynylplatinum(ii) Complexes......Page 538
Pt(iii) Complexes......Page 568
Pt(iv) Complexes......Page 570
References......Page 597
Platinum-Carbon pi-Bonded Complexes......Page 610
Preparation......Page 611
Structural aspects......Page 613
Oxidative additions......Page 614
Preparation via bridge cleavage......Page 616
Preparation using electrophilic species and/or creating vacant coordination sites......Page 617
Pentacoordinate complexes......Page 618
Structural aspects......Page 619
Reactions with nucleophiles......Page 621
Migratory alkene insertion......Page 622
Oxidative addition......Page 623
Theoretical aspects......Page 624
eta2-Monoalkene Complexes (Polydentate)......Page 625
Preparation......Page 627
Preparation......Page 628
Diene displacement......Page 629
eta2-Allene and cumulene derivatives......Page 630
Complexes of eta2-X=CR2 and related derivatives......Page 631
eta2-Polyalkene Complexes (Conjugated)......Page 632
eta2-Fullerene and Related Complexes......Page 633
Homobimetallic complexes......Page 634
Heterobimetallic complexes......Page 636
Homometallic complexes......Page 637
Preparation......Page 638
Interaction with acid (H+) or related electrophilic species......Page 640
Preparation......Page 641
Theoretical aspects......Page 642
eta2-Arynes and Strained Cyclic Alkynes......Page 643
Homobimetallic complexes......Page 644
Heterobimetallic derivatives......Page 646
Homometallic complexes......Page 647
Heterometallic complexes......Page 649
Preparation......Page 650
Addition reactions to propargyl/allenyl or trimethylenemethane complexes......Page 651
Structural aspects......Page 653
Theoretical aspects......Page 654
eta3-Butadienyl complexes......Page 655
eta3-Propargyl/allenyl complexes......Page 656
Bimetallic Complexes......Page 657
eta4-1,3-Diene Complexes......Page 658
Divalent derivatives......Page 659
Tetravalent derivatives......Page 661
eta5-Boron-carbon ligands......Page 662
References......Page 663

This new edition continues how the subject of organic synthesis was treated in the original in terms of functional group transformations, and it brings in all the new developments from the literature since the last version was published. It is truly a comprehensive, encyclopedic overview of all known (and as yet unknown) functional groups. The material is easily accessible and provides essential references to methodologies for the interconversion of functional groups in organic synthesis. The references provide entry into the key literature and background necessary for anyone designing a new synthetic procedure. Organic and inorganic chemists who work in academia, industry, and government will find this series of books invaluable in their work

v. 1. Fundamentals
v. 2. Compounds of groups 1-2 and 11-12
v. 3. Compounds of groups 13 to 15
v. 4. Compounds of groups 3-4 and the f elements
v. 5. Compounds of groups 5-7
v. 6. Compounds of groups 8
v. 7. Compounds of groups 9
v. 8. Compounds of groups 10
v. 9. Applications I, main group compounds in organic synthesis
v. 10. Applications II, transition metal compounds in organic synthesis 1
v. 11. Applications II, transition metal compounds in organic synthesis 2
v. 12. Applications III, functional materials, environmental and biological applications
v. 13. Cumulative subject index.

2013-03-30